Degradación de colorantes el soluciones acuosas utilizando plasma jet atmosférico
Palabras clave:
plasma jet atmosférico, degradación de colorantes, tratamiento de agua, contaminación con colorantes, industria textilResumen
Se investigó la capacidad de un plasma jet atmosférico, alimentado con aire, para degradar cinco colorantes orgánicos en soluciones acuosas. El estudio se realizó siguiendo un diseño experimental de laboratorio con réplicas por triplicado, evaluando la degradación visualmente y mediante espectrofotometría UV-Vis. Los resultados demuestran que la eficiencia de degradación está relacionada con la estructura química de los colorantes. A partir de concentraciones iniciales del orden de 5 a 10 mg/L, el verde malaquita, con una concentración inicial de 3.74 mg/L, experimentó la mayor remoción (88%), seguido por el rojo congo, con 9.92 mg/L, que tuvo una remoción del (75%) y el naranja de metilo, con 7.61 mg/L, que alcanzó una remoción del (72%). El rojo de metilo, con 5.48 mg/L, mostró una respuesta moderada (37%), mientras que el azul de metileno, con 6.38 mg/L, fue altamente resistente, con una degradación mínima de solo el 1%. El uso de aire como gas de proceso es una ventaja significativa, ya que elimina los costos asociados a gases nobles y genera simultáneamente especies reactivas de oxígeno y nitrógeno (ROS/RNS) que actúan como agentes oxidantes. Los resultados concuerdan con la literatura existente, validando el desempeño del reactor y sugiriendo que el plasma jet es una tecnología viable para el tratamiento de efluentes industriales, especialmente en las industrias textil y de curtidurías. Se realizarán estudios futuros para cuantificar la posible fotodegradación y caracterizar los subproductos.
Referencias
Al-Tohamy, R., Ali, S. S., Li, F., Okasha, K. M., Mahmoud, Y. A.-G., Elsamahy, T., Jiao, H., Fu, Y., & Sun, J. (2022). A critical review on the treatment of dye-containing wastewater: Ecotoxicological and health concerns of textile dyes and possible remediation approaches for environmental safety. Ecotoxicology and Environmental Safety, 231: 113160. https://doi.org/10.1016/j.ecoenv.2021.113160
Arora, S. (2014). Textile dyes: It’s impact on environment and its treatment. Journal of Bioremediation & Biodegradation, 05(03):1000e146. https://doi.org/10.4172/2155-6199.1000e146
Attri, P., Yusupov, M., Park, J. H., Lingamdinne, L. P., Koduru, J. R., Shiratani, M., Choi, E. H., & Bogaerts, A. (2016). Mechanism and comparison of needle-type non-thermal direct and indirect atmospheric pressure plasma jets on the degradation of dyes. Scientific Reports, 6(1): 34419. https://doi.org/10.1038/srep34419
Chavan, U., & Patil, S. (2024). Water treatment using atmospheric pressure plasma: dielectric barrier discharge and corona discharge method, and reactive species analysis. E3S Web of Conferences, 559: 03006. https://doi.org/10.1051/e3sconf/202455903006
García, M. C., Mora, M., Esquivel, D., Foster, J. E., Rodero, A., Jiménez-Sanchidrián, C., & Romero-Salguero, F. J. (2017). Microwave atmospheric pressure plasma jets for wastewater treatment: Degradation of methylene blue as a model dye. Chemosphere, 180: 239–246. https://doi.org/10.1016/j.chemosphere.2017.03.126
Giardina, A., Lofrano, G., Libralato, G., Siciliano, A., Marotta, E., & Paradisi, C. (2024). Air non-thermal plasma, a green approach for the treatment of contaminated water: the case of sulfamethoxazole. Frontiers in Environmental Chemistry, 5: 1416702. https://doi.org/10.3389/fenvc.2024.1416702
Hu, Y., Li, Y., He, J., Liu, T., Zhang, K., Huang, X., Kong, L., & Liu, J. (2018). EDTA-Fe(III) Fenton-like oxidation for the degradation of malachite green. Journal of Environmental Management, 226: 256–263. https://doi.org/10.1016/j.jenvman.2018.08.029
Klumpara, R., Ngamjarurojana, A., & Boonyawan, D. (2023). Study of hydroxyl and nitrite radicals concentration in plasma-activated water by photoluminescence spectroscopy. Journal of Physics: Conference Series, 2653(1): 012010. https://doi.org/10.1088/1 742-6596/2653/1/012010
Kumar, A., Škoro, N., Gernjak, W., Povrenović, D., & Puač, N. (2022). Direct and indirect treatment of organic dye (acid blue 25) solutions by using cold atmospheric plasma jet. Frontiers in Physics, 10: 835635. https://doi.org/10.3389/fphy.2022.835635
Kyere-Yeboah, K., Bique, I. K., & Qiao, X. (2023). Advances of non-thermal plasma discharge technology in degrading recalcitrant wastewater pollutants: A comprehensive review. Chemosphere, 320: 138061. https://doi.org/10.1016/j.chemosphere.2023.138061
Navaneetha Pandiyaraj, K., Vasu, d., Padmanabhan, P. V. A., Pichumani, M., Deshmukh, R. R., & Kandavelu, V. (2020). Evaluation of influence of cold atmospheric pressure argon plasma operating parameters on degradation of aqueous solution of Reactive Blue 198 (RB-198). Plasma Science and Technology, 22(5): 055504. https://doi.org/10.1088/2 058-6272/ab568d
Neira-Velázquez, M. G., Ku-Herrera, J. de J., Narro-Céspedes, R. I., Flores-Villaseñor, S. E., Cortez-Garza, Y. L., Cuellar-Gaona, C. G., & Soria-Arguello, G. (2024). Carbon nanostructures synthesis by catalyst-free atmospheric pressure plasma jet. Journal of Physics D: Applied Physics, 57(31): 315302. https://doi.org/10.1088/1361-6463/ad44a6
Okoniewska, E. (2021). Removal of selected dyes on activated carbons. Sustainability, 13(8): 4300. https://doi.org/10.3390/su13084300
Porjai, P., Wattanawikkam, C., Bootchanont, A., Barnthip, N., Pavasupree, S., Jitjing, P., Boonyawan, D., & Kachayut, K. (2023). Discharge duty cycles effects of 20 kHz air atmospheric pressure plasma jet on methylene blue solution degradation. Suranaree Journal of Science and Technology, 30(2): 239. https://doi.org/10.55766/sujst-2023-02-e01585
Raji, A., Vasu, D., Navaneetha Pandiyaraj, K., Ghobeira, R., & Deshmukh, R. R. (2022). Degradation and detoxification of remazol blue contaminants as a model textile effluent via advanced nonthermal plasma oxidation processes. IEEE Transactions on Plasma Science, 50(6): 1407–1415. https://doi.org/10.1109/TPS.2022.3147544
Salazar, L. F. C., Delgado, V. J. C., Guía, T. E. F., & Argüello, G. S. (2024). Removal of dyes from water: Techniques and materials. Sustainable Agriculture and Global Environmental Health (pp: 93–130). Apple Academic Press. https://doi.org/10.1201/9 781003504474-5
Saqib, S., Muneer, A., Munir, R., Sayed, M., Waqas, M., Aliyam, T., Younas, F., Farah, M. A., Elsadek, M. F., & Noreen, S. (2024). Green hybrid coagulants for water treatment: An innovative approach using alum and bentonite clay combined with eco-friendly plant materials for batch and column adsorption. Environmental Research, 259: 119569. https://doi.org/10.1016/j.envres.2024.119569
Sarkar, S., Echeverría-Vega, A., Banerjee, A., & Bandopadhyay, R. (2021). Decolourisation and biodegradation of textile di-azo dye congo red by chryseobacterium geocarposphaerae DD3. Sustainability, 13(19): 10850. https://doi.org/10.3390/su131910850
Shindhal, T., Rakholiya, P., Varjani, S., Pandey, A., Ngo, H. H., Guo, W., Ng, H. Y., & Taherzadeh, M. J. (2021). A critical review on advances in the practices and perspectives for the treatment of dye industry wastewater. Bioengineered, 12(1): 70–87. https://doi.org/10.1080/21655979.2020.1863034
Tkaczyk, A., Mitrowska, K., & Posyniak, A. (2020). Synthetic organic dyes as contaminants of the aquatic environment and their implications for ecosystems: A review. Science of The Total Environment, 717: 137222. https://doi.org/10.1016/j.scitotenv.2020.137222
Wilayat, S., Fazil, P., Khan, J. A., Zada, A., Ali Shah, M. I., Al-Anazi, A., Shah, N. S., Han, C., & Ateeq, M. (2024). Degradation of malachite green by UV/H2O2 and UV/H2O2/Fe2+ processes: kinetics and mechanism. Frontiers in Chemistry, 12: 1467438. https://doi.org/10.3389/fchem.2024.1467438
Zhou, R., Zhang, T., Zhou, R., Mai-Prochnow, A., Ponraj, S. B., Fang, Z., Masood, H., Kananagh, J., McClure, D., Alam, D., Ostrikov, K. (Ken), & Cullen, P. J. (2021). Underwater microplasma bubbles for efficient and simultaneous degradation of mixed dye pollutants. Science of The Total Environment, 750: 142295. https://doi.org/10.1016/j.scito tenv.2020.142295