Revisión sobre la producción, usos y revalorización de escorias

Autores/as

  • Danay Alexandra Charles Alexandra Charles Escuela Superior de Ingeniería "Lic. Adolfo López Mateos", Unidad Norte, UAdeC Autor/a
  • Adrián Amilcare González-Ibarra Escuela Superior de Ingeniería "Lic. Adolfo López Mateos", Unidad Norte, UAdeC Autor/a
  • Gloria Ivone Dávila Pulido Escuela Superior de Ingeniería "Lic. Adolfo López Mateos", Unidad Norte, UAdeC Autor/a
  • Armando Salinas-Rodríguez CINVESTAV Unidad Saltillo Autor/a

Palabras clave:

metales preciosos, escoria, residuo, medio ambiente

Resumen

Los residuos sólidos de los procesos pirometalúrgicos conocidos como “escorias” son de naturaleza y características muy variadas; sus características dependen de su origen (materia prima de la que provienen), composición química y propiedades físicas. Asimismo, las escorias son de gran interés debido a las restricciones medioambientales actuales y a las aplicaciones emergentes, resultado de la necesidad de ser más competitivos sin comprometer al entorno. De acuerdo con la bibliografía las escorias contienen elementos o compuestos de valor comercial, principalmente metales básicos y preciosos. El uso más común es como material para la construcción de caminos, pero también se ha reportado su uso como materia prima en la producción de cemento Portland, reemplazando parcialmente el Clinker.

Referencias

Abdul-Wahab, S. A. y Marikar, F. A. (2012). The environmental impact of gold mines: pollution by heavy metals. Central European Journal of Engineering. 2: 304-313. DOI: 10.2478/s13531-011-0052-3

Acosta, A., Aineto, M., Iglesias, I. (2001). Physico-chemical characterization of slag waste coming from IGCCthermal power plant. Materials Letters. 50: 246-250. DOI: 10.1016/S0167-577X(01)00233-6

Akcil, A., (2003). Destruction of cyanide in gold mill effluents: biological versus chemical treatments. Biotechnology Advances. 21: 501-510. DOI: 10.1016/S0734- 9750(03)00099-5

Adams, M. D. (2016). Gold Ore Processing. Project Development and Operations. DOI: 10.1016/C2015-0-00699-2

Avarmaa, K., O’Brien, H., Klemettinen, L., Taskinen, P. (2020). Precious metal recoveries in secondary copper smelting with high-alumina slags. Journal of Material Cycles and Waste Management. 22: 642–655. DOI: 10.1007/s10163-019-00955-w

Ban J., Sun, K. Yao J., Sunahara G., Hudson-Edwards K., Jordan G., Alakangas L., Ni W., Chi-Sun P. (2022). Advances in the use of recycled non-ferrous slag as a resource for non-ferrous metal mine site remediation. Environmental Research. 213: 113533. DOI: 10.1016/j.envres.2022.113533

Bas, A. D., Ghali, E., Choib, Y. (2017). A review on electrochemical dissolution and passivation of gold during cyanidation in presence of sulphides and oxides. Hydrometallurgy 172: 30–44. DOI: 10.1016/j.hydromet.2017.06.021

Bazan, V., Brandaleze, E., Valentini, M., Hidalgo, N. (2015). Characterization of Slags Produced During Gold Melting Process. Procedia Materials Science. 8: 851 – 860. DOI: 10.1016/j.mspro.2015.04.145

Botz, M. M., Mudder, T. I. (2002). Treatment of solutions and slurries for cyanide removal. En M. C. Adams (Ed.), Mineral Processing Plant Design, Practice and Control (Second Edition). The Society for Mining, Metallurgy, and Exploration. 474.

Botz, M.M., Mudder T.I., y Akcil A.U. (2016). Cyanide Treatment: Physical, Chemical, and Biological Processes In: Gold Ore Processing (Second Edition). Project Development and Operations. 619-645.

Chen, J., Yan, B., Li, H., Li, P., Guo, H. (2018). Vitrification of blast furnace slag and fluorite tailings for giving diopside-fluorapatite glass-ceramics. Materials Letters. 218: 309-312. DOI: 10.1016/j.matlet.2018.02.020

Chi, G., Fuerstenau, M. C., Marsden, J. O. (1997). Study of Merrill-Crowe processing. Part I: Solubility of zinc in alkaline cyanide solution. International Journal of Mineral Processing. 49: 171-183. DOI: 10.1016/S0301-7516(96)00043-9

Chu, J.P., Hwang, I.J., Tzeng, C.C., Kuo, Y.Y., Yu, Y.J. (2018). Characterization of vitrified slag from mixed medical waste surrogates treated by a thermal plasma system. Journal of Hazardous Materials. 58: 179–194. DOI: 10.1016/S0304- 3894(97)00130-1

Criado, M., Ke, X., Provis, J. L., Bernal, S. A. (2017). Alternative inorganic binders based on alkali-activated metallurgical slags. Sustainable and Nonconventional Construction Materials using Inorganic Bonded Fiber Composites. 185-220. DOI: 10.1016/B978-0-08-102001-2.00008-5

Cui, J. y Roven, H. J. (2011). Waste In: A Handbook for Management. Electronic Waste. 281-296. DOI: 10.1016/B978-0-12-381475-3.10020-8

Dong, K., Xie, F., Wang, W., Chang, Y., Lu, D., Gu, X., Chen, C. (2021). The detoxification and utilization of cyanide tailings: A critical review. Journal of cleaner production. 302: 15. DOI: 10.1016/j.jclepro.2021.126946

Douglas, E. y Zerbino, R. (1986). Characterization of granule and pelletized blast furnace slag. Cement and concrete research. 16: 662-670. DOI:10.1016/0008- 8846(86)90039-6

Dunn, J. B., Gaines, L., Sullivan, J. y Wang M. Q. (2012). Impact of Recycling on Cradle-to-Gate Energy Consumption and Greenhouse Gas Emissions of Automotive Lithium-Ion Batteries. Environmental Science & Technology. 46: 12704-12710. DOI: 10.1021/es302420z

Gamboa-Hernández, A., Parga-Torres J. R., y Moreno Casillas H. A. (2018). Recovery of silver from slags generated by melting precipitates from the Merrill– Crowe process. Canadian Metallurgical Quarterly. DOI: 10.1080/00084433.2018.1544342

González-Ibarra, A.A., Nava-Alonso, F., Fuentes-Aceituno, J.C., Uribe-Salas, A. (2016). Hydrothermal decomposition of industrial jarosite in alkaline media: the rate determining step of the process kinetics. Journal of Mining and Metallurgy. 52: 135-

142. DOI: 10.2298/JMMB150430016G

Habashi, F. (1997). Handbook of Extractive Metallurgy, Vol. II and III. Wiley-VCH.

Hylander, L. D. y Herbert R. B. (2008). Global Emission and Production of Mercury during the Pyrometallurgical Extraction of Nonferrous Sulfide Ores. Environmental Science & Technology. 42: 5971–5977. DOI: 10.1021/es800495g

International Cyanide Management Institute (2021). The International Cyanide Management Code. Disponible en: www.cyanidecode.org

Kanari, N.E., Allair, I., Gaballah, A., Garcia, F. (1999). Characterization of polluting elements in slag from the incineration of waste from the chemical and metallurgical industry. Revista de Metalurgia (Madrid). 35: 3-10

Kinnunen, P., Karhu, M., Yli-Rantala, E., Kivikytö-Reponen, P., Mäkinen, J. (2022). A review of circular economy strategies for mine tailings. Cleaner Engineering and Technology. 8: 100449

Kuyucak N., Akcil A., (2013). Cyanide and removal options from effluents in gold mining and metallurgical processes. Minerals Engineering. 50: 13-29. DOI: 10.1016/j.mineng.2013.05.027

Ledin, M., y Pedersen, K. (1996). The environmental impact of mine wastes — Roles of microorganisms and their significance in treatment of mine wastes. Earth-Science Reviews. 41: 1–2, 67-108. DOI: 10.1016/0012-8252(96)00016-5

Li, Z., Li, J., Spooner, S., Seetharaman, S. (2021). Basic Oxygen Steelmaking Slag: Formation, Reaction, and Energy and Material Recovery. Materials Recovery. Steel research international. DOI: 10.1002/srin.202100167

Liu, T., Xie, Y., Guo, X., Zhang, J., Zhu, L., Luo, Z., Tang, Y., Lu, A. (2021). The role and stabilization behavior of heavy metal ions in eco-friendly porous semi-vitrified ceramics for construction application. Journal of Cleaner Production. 292: 1-17. DOI: 10.1016/j.jclepro.2021.125855

Luna, R. M. y Lapidus, G. T. (2000). Cyanidation kinetics of silver sulfide.

Hydrometallurgy, 56: 171–188. DOI: 10.1016/s0304-386x(00)00072-4

Marsden, J. O., y House, C. I., (2006). Chemistry of Gold Extraction (Second Edition). Society for Mining, Metallurgy, and Exploration. 120

Mills, K. Yuan, L., Jones, R.T. (2011). The estimation of slag properties. Journal of the Southern African Institute of Mining and Metallurgy. 110: 649-658

Mudder, T. I., Botz, M. M. y Smith, A. (2001). Chemistry and treatment of cyanidation wastes. Mining Journal books LTD London.

Muller, A., Blachnik, R. (2002). Reactivity in the system copper–arsenic–sulfur I. The formation of Cu3AsS4, enargite. Thermochemical. 387: 153–171.

Nava-Alonso, F., Elorza-Rodríguez, E., Uribe-Salas, A., Pérez-Garibay, R. (2007). Análisis químico de cianuro en el proceso de cianuración: revisión de los principales métodos. Revista de Metalurgia, 43: 20-28.

Norma Oficial Mexicana NOM-157-SEMARNAT-2009, Que establece los elementos y procedimientos para instrumentar planes de manejo de residuos mineros. Diario Oficial.

Nowinska, K. (2020). Mineralogical and Chemical Characteristics of Slags from the Pyrometallurgical Extraction of Zinc and Lead. Minerals. 10: 371. DOI: 10.3390/min10040371

Pan, F., Lv, X., He, W., Pei, G. (2020). Preparation of Expanded Slag Ball with Blast Furnace Slag by Rotary Cup. In: Peng, Z., et al. 11th International Symposium on High-Temperature Metallurgical Processing. The Minerals, Metals & Materials Series. Springer, Cham. DOI: 10.1007/978-3-030-36540-0_29

Panesar D. K. (2019). Supplementary cementing materials. Developments in the Formulation and Reinforcement of Concrete (Second Edition) Woodhead Publishing Series in Civil and Structural Engineering. 55-85

Pasetto, M. y Baldo, N. (2010). Experimental evaluation of high-performance base course and road base asphalt concrete with electric arc furnace steel slags. Journal of Hazardous Materials. 181: 938-948. DOI: 10.1016/j.jhazmat.2010.05.104

Puertas, F. (1995). Cementos de escorias activadas alcalinamente: Situación actual y perspectivas de futuro. Materiales de construcción, 45: 53-64.

Rai, V., Liu, D., Xia, D., Jayaraman, Y., Gabriel, J.-C.P. (2021). Electrochemical Approaches for the Recovery of Metals from Electronic Waste: A Critical Review. Recycling, 6: 53. DOI: 10.3390/recycling6030053

Reith, F., Zammit, C.M., Rogers, S.L. (2012). Potential utilization of microorganism in gold processing: a review. Mineral Processing and Extractive Metallurgy, 121: 251-260. DOI: 10.1179/1743285512Y.0000000017

Sánchez, M., Parada, F., Parra, R., Marquez, F., Jara, R., Carrasco, J.C., y Palacios,

J. (2004). Management of copper pyrometallurgical slags: giving additional value to copper mining industry. The South African Institute of Mining and Metallurgy. VII International Conference on Molten Slags Fluxes and Salts.

Santacruz-Torres, J. y Torres-Agredo J. (2019). Aprovechamiento de escorias de fundición secundaria de plomo en ladrillos cerámicos. Ciencia e Ingeniería Neogranadina. 29: 8-18. DOI: 10.18359/rcin.3495

Sarfo, P., Wyss, G., Ma, G, Das A., Young, C. (2017). Carbothermal reduction of copper smelter slag for recycling into pig iron and glass. Minerals Engineering. 107: 8-19. DOI: 10.1016/j.mineng.2017.02.006

Shi, C., Meyer, C., & Behnood, A. (2008). Utilization of copper slag in cement and concrete. Resources, Conservation and Recycling. 52: 1115–1120. DOI: 10.1016/j.resconrec.2008.06.008

Souza, A.J., Pinheiro, B.C.A., Holanda J.N.F. (2010). Recycling of gneiss rock waste in the manufacture of vitrified floor tiles. Journal of Environmental Management. 91: 685-689. DOI: 10.1016/j.jenvman.2009.09.032

Tzen-Chin, L., Wei-Jer, W., Ping-Yu, S. (2008). Slag–cement mortar made with cement and slag vitrified from MSWI fly-ash/scrubber-ash and glass frit. Construction and Building Materials. 22: 1914–1921. DOI: 10.1016/j.conbuildmat.2007.07.030

Vilchis-Carbajal, S., Gonzalez, I. y Lapidus, G. T. (2000). An electrochemical study of gold cementation with zinc powder at low cyanide concentration in alkaline solutions. Journal of Applied Electrochemistry. 30: 217-229. DOI: 10.1023/A:1003820807315

Wang, G. C. (2016). Nonferrous metal extraction and nonferrous slags. The Utilization of Slag in Civil Infrastructure Construction. 35-61

Yannopoulos, J. C. (1991). Cyanidation of Gold Ores In Yannopoulos J. C., The extractive metallurgy of gold, 1st Ed. New York, USA. Van Nostrand Reinhold. 141- 168

Yung-Chin, D., Yin-Shya, F., Ta-Wui, C. (2016). Preparation and characterization of vitrified slag/geopolymers for construction and fire-resistance applications. Materials and Structures. 49: 1883–1891. DOI: 10.1617/s11527-015-0620-8

Yuskel, I. (2018). Blast-furnace slag. Waste and Supplementary Cementitious Materials in Concrete. 361-415. DOI: 10.1016/B978-0-08-102156-9.00012-2

Zhang, L., Malfliet, A., Blanpain, B., Guo M. (2022). Understanding the relationship between slag crystallization behaviour and electrical conductivity under isothermal conditions for online slag solidification monitoring in slag recycling. Resources, Conservation and Recycling. 182: 106-319. DOI: 10.1016/j.resconrec.2022.106319

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Publicado

09/02/2025

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Artículos de Investigación

Cómo citar

Alexandra Charles, D. A. C., González-Ibarra, A. A., Dávila Pulido, G. I., & Salinas-Rodríguez, A. (2025). Revisión sobre la producción, usos y revalorización de escorias. Cienciacierta, 20(77), 221-250. https://revistas.uadec.mx/CienciaCierta/article/view/393