Cáscara de nuez para la remoción por absorción de azul de metileno en solución acuosa
Palabras clave:
Azul de metileno, Cáscara de nuez, Cinética, Equilibrio, Isoterma de adsorción.Resumen
Se utilizó cáscara de nuez (CN) como material adsorbente agrícola para eliminar el azul de metileno (AM) de soluciones acuosas y se evaluó en un proceso discontinuo. CN se analizó mediante microscopía electrónica de barrido (MEB) e infrarrojo por transformadas de Fourier (IR-TF). Los experimentos se realizaron dependiendo del tiempo de contacto, la dosis de adsorbente (0,5 y 0,1 g), la agitación (50 y 100 rpm) y la temperatura (293 y 313 K), concentración inicial del adsorbato (50 mg/L). Los datos cinéticos se analizaron utilizando ecuaciones de pseudo primer y pseudo segundo orden. Los datos isotérmicos se modelaron con las ecuaciones de Langmuir y Freundlich. Los datos de la isoterma de adsorción encajan bien con la isoterma de Langmuir y se encontró que la capacidad de adsorción de la monocapa era de 80,65 mg/g para AM. La adsorción de AM en CN se confirma mediante IRTF y MEB. El estudio termodinámico revela que la adsorción de AM en CN se realiza mediante una reacción endotérmica (ΔH = 1.097 kJ/mol), factible y espontánea (ΔG0 = -21,157.32 kJ/mol a 293 K; -23,363.13 kJ/mol a 303 K; y -17,333.87 kJ/mol a 313 K) y disminuye el desorden de las moléculas. En el proceso de adsorción (ΔS0 = -2,63 kJ/mol K). La eficiencia del CN en AM estuvo relacionada con la disposición de los sitios de adsorción, así como con la estructura microporosa del material adsorbente. Los resultados indicaron que la cáscara de nuez podría ser una alternativa a los adsorbentes más caros que se utilizan para eliminar este colorante.
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